Water-Soluble Pentagonal-Prismatic Titanium-Oxo Clusters
Release Time:2019-06-12
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- Title of Paper:
- Water-Soluble Pentagonal-Prismatic Titanium-Oxo Clusters
- Summary:
- By using solubility control to crystallize the prenucleation clusters of hydrosol, a family of titanium-oxo clusters possessing the {Ti18O27} core in which the 18 Ti(IV)-ions are uniquely connected with μ-oxo ligands into a triple-decked pentagonal prism was obtained. The cluster cores are wrapped by external sulfate and aqua ligands, showing good solubilities and stabilities in a variety of solvents including acetonitrile and water and allowing their solution chemistry being studied by means of electrospray ionization mass spectroscopy, 17O NMR, and vibrational spectroscopy. Furthermore, this
- Correspondence Author:
- Guanyun Zhang, Caiyun Liu, De-Liang Long, Leroy Cronin, Chen-Ho Tung, and Yifeng Wang*
- Volume:
- 138
- Issue:
- 35
- Page Number:
- 11097–11100
- Translation or Not:
- No
- Date of Publication:
- 2016-08
- Links to Published Journals:
- https://pubs.acs.org/doi/abs/10.1021/jacs.6b06290
- Release Time:
- 2019-06-12