Interfacial charge transfer in a functionalized polyoxotitanate cluster
Release Time:2019-06-12
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- Title of Paper:
- Interfacial charge transfer in a functionalized polyoxotitanate cluster
- Summary:
- Understanding the charge transfer processes at the dye/TiO2 interface is often modeled using catechol/TiO2 systems. However, it indeed require precise structural information. In order to simulate the dye/TiO2 systems at a molecular level, herein we report the synthesis and structure of a novel titanium oxo-cluster [Ti4O(OiPr)6(DTBC)4] (1) functionalized with 3,5-di-tert-butylcatechol (DTBC). UV–Vis spectroscopy, electron spin resonance (ESR), X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations show that 1 exhibits property of Ti(III) which is caused by subst
- Correspondence Author:
- Jie Hou, Qun Zhang, Yufei Wu, Yuliang Liu, Lin Du, Chen-Ho Tung, Yifeng Wang
- Document Code:
- 017
- Page Number:
- 279-283
- Translation or Not:
- No
- Date of Publication:
- 2016-06
- Links to Published Journals:
- https://www.sciencedirect.com/science/article/pii/S0020169316000281
- Release Time:
- 2019-06-12